Scalable continuous solvothermal synthesis of metal organic framework (MOF-5) crystals
نویسندگان
چکیده
منابع مشابه
Synthesis of magnetic metal-organic framework (MOF) for efficient removal of organic dyes from water
A novel, simple and efficient strategy for fabricating a magnetic metal-organic framework (MOF) as sorbent to remove organic compounds from simulated water samples is presented and tested for removal of methylene blue (MB) as an example. The novel adsorbents combine advantages of MOFs and magnetic nanoparticles and possess large capacity, low cost, rapid removal and easy separation of the solid...
متن کاملThermal conductivity of metal-organic framework 5 (MOF-5): Part I. Molecular dynamics simulations
The phonon thermal conductivity of MOF-5, a metal-organic framework crystal with a phenylene bridge, is predicted between temperatures of 200 K and 400 K using molecular dynamics simulations and the Green–Kubo method. The simulations are performed using interatomic potentials obtained using ab initio calculations and experimental results. The predicted thermal conductivity of MOF-5 is low for a...
متن کاملResin-assisted solvothermal synthesis of metal-organic frameworks.
Transition metal-exchanged polymer resin beads have been used as a heterogeneous controlled-release source of metal cations in high yielding, phase pure solvothermal syntheses of novel transition metal-organic frameworks.
متن کاملThermodynamics of solvent interaction with the metal-organic framework MOF-5.
The inclusion of solvent in metal-organic framework (MOF) materials is a highly specific form of guest-host interaction. In this work, the energetics of solvent MOF-5 interactions has been investigated by solution calorimetry in 5 M sodium hydroxide (NaOH) at room temperature. Solution calorimetric measurement of enthalpy of formation (ΔH(f)) of Zn4O(C8H4O4)3·C3H7NO (MOF-5·DMF) and Zn4O(C8H4O4)...
متن کاملThermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
The thermal conductivity of MOF-5 single crystals is measured over a wide temperature range between 6 K and 300 K, using the longitudinal, steady-state heat flow method. Between 6 K and 20 K, the thermal conductivity increases with the increase in temperature and exhibits a peak near 20 K. This peak results from the crossover between the decreasing mean free path and the increasing phonon speci...
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ژورنال
عنوان ژورنال: Chemical Engineering Journal
سال: 2016
ISSN: 1385-8947
DOI: 10.1016/j.cej.2015.10.023